000 02462nab a22003377a 4500
001 67887
003 MX-TxCIM
005 20250407163042.0
008 240909s1987 -uk|||p|op||| 00| 0 eng d
022 _a1060-3271
022 _a1944-7922 (Online)
024 8 _ahttps://doi.org/10.1093/jaoac/70.1.160
040 _aMX-TxCIM
041 _aeng
100 1 _aGehrke, C.W.
_936580
245 1 0 _aAnalysis of amino acids by gas chromatography as the N-Trifluoroacetyl η-Butyl esters
260 _aUnited Kingdom :
_bOxford University Press,
_c1987.
500 _aPeer review
520 _aThis presentation describes amino acid analysis with the gas chromatographic method and experimental conditions using the N-trifluoroacetyl n-butyl ester derivatives; the study we describe here was undertaken to compare gas chromatographic (GC) and ion-exchange chromatographic (IEC) analyses of amino acids in hydrolysates of 9 diverse sample types to gain insight into effects of these 2 chromatographic methods of analysis on variation in amino acid results. Our study showed that values for samples prepared by 2 separate laboratories using the same procedure were generally in good agreement when all of the hydrolysates were analyzed by a single laboratory using a single method of analysis. To compare results from gas chromatography with those from ion-exchange chromatography analyses were performed by 2 different laboratories on the same hydrolysates and on different hydrolysates prepared by the same method by both laboratories. The data demonstrate that GC and IEC can be expected to yield essentially identical results when applied to the same hydrolysate. Agreement is so close that interlaboratory differences in hydrolysate preparation of the same sample contribute as much to variation in amino acid results as does the method of analysis, a fact which should be noted in planning collaborative studies.
546 _aText in English
650 7 _aAnalysis
_2AGROVOC
_927824
650 7 _aAmino acids
_2AGROVOC
_94464
650 7 _aGas chromatography
_2AGROVOC
_911840
650 7 _aNitrogen
_2AGROVOC
_92912
650 7 _aIon exchange
_2AGROVOC
_928018
700 1 _aKuo, K.C.
_936733
700 1 _aKaiser, F.E.
_936734
700 1 _aZumwalt, R.W.
_936584
773 0 _dUnited Kingdom : Oxford University Press, 1987.
_gv. 70, no. 1, p. 160–170
_tJournal of Association of Official Analytical Chemists
_wG446038
_x1060-3271
942 _2ddc
_cJA
_n0
999 _c67887
_d67879