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022 _a0962-8436
022 _a1471-2970 (Online)
024 8 _ahttps://doi.org/10.1098/rstb.2011.0313
040 _aMX-TxCIM
041 _aeng
100 1 _aSmith, K.A.
_912844
245 1 4 _aThe role of N2O derived from crop-based biofuels, and from agriculture in general, in Earth's climate
260 _aLondon (United Kingdom) :
_bThe Royal Society,
_c2012.
500 _aPeer review
520 _aIn earlier work, we compared the amount of newly fixed nitrogen (N, as synthetic fertilizer and biologically fixed N) entering agricultural systems globally to the total emission of nitrous oxide (N2O). We obtained an N2O emission factor (EF) of 3–5%, and applied it to biofuel production. For ‘first-generation’ biofuels, e.g. biodiesel from rapeseed and bioethanol from corn (maize), that require N fertilizer, N2O from biofuel production could cause (depending on N uptake efficiency) as much or more global warming as that avoided by replacement of fossil fuel by the biofuel. Our subsequent calculations in a follow-up paper, using published life cycle analysis (LCA) models, led to broadly similar conclusions. The N2O EF applies to agricultural crops in general, not just to biofuel crops, and has made possible a top-down estimate of global emissions from agriculture. Independent modelling by another group using bottom-up IPCC inventory methodology has shown good agreement at the global scale with our top-down estimate. Work by Davidson showed that the rate of accumulation of N2O in the atmosphere in the late nineteenth and twentieth centuries was greater than that predicted from agricultural inputs limited to fertilizer N and biologically fixed N (Davidson, E. A. 2009 Nat. Geosci. 2, 659–662.). However, by also including soil organic N mineralized following land-use change and NOx deposited from the atmosphere in our estimates of the reactive N entering the agricultural cycle, we have now obtained a good fit between the observed atmospheric N2O concentrations from 1860 to 2000 and those calculated on the basis of a 4 per cent EF for the reactive N.
546 _aText in English
650 7 _aNitrous oxide
_2AGROVOC
_94669
650 7 _aBiofuels
_2AGROVOC
_97324
650 7 _aAgriculture
_gAGROVOC
_2
_91007
650 7 _aEmission
_2AGROVOC
_911417
650 7 _aLife Cycle Analysis
_2AGROVOC
_98633
700 1 _aMosier, A.R.
_916847
700 1 _aCrutzen, P.J.
_912847
700 1 _aWiniwarter, W.
_916848
773 0 _dLondon (United Kingdom) : The Royal Society, 2012.
_x0962-8436
_gv. 367, no. 1593, p. 1169-1174
_tPhilosophical Transactions of the Royal Society of London. Series B, Biological Sciences
_wu444862
942 _cJA
_n0
_2ddc